English Premier League leaders Liverpool against defending French champions PSG promises to be an intriguing tie.
PSG looked to be heading out of the competition before a late run of form saw them finish 15th in the league phase.
They lost to Arsenal before defeating Manchester City to set up an all-France knockout phase play-off with Brest which they won 10-nil on aggregate.
Liverpool have not won any of their past five away games against French clubs, since a Champions League victory against Marseille in 2008.
Former Reds defender Stephen Warnock, says Arne Slot men would have preferred to face Benfica in the round of 16.
Stephen Warnock.
Meanwhile, Arsenal take on PSV Eindhoven. Commentator, Harry Symeou, says despite Arsenal injury worries the Gunners should come out on top.
Harry Symeou.
The other fixtures will feature Aston Villa against Club Brugge.
Holders Real Madrid – who knocked out Manchester City in the knockout phase play-offs – face local rivals Atletico Madrid and Bayern Munich play Bayer Leverkusen in an all-Germany affair.
The two-legged last 16 ties will be played on March 4 and 5 and March 11 and 12.
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